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Bromine Water Test

Predict major...

Question

Predict major addition product when the following addition reaction carried out in presence of peroxide.

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Solution

The correct option is A 1
A molecule of chloroform is added to alkene to form trichloro derivative of alkane
When peroxide is present, Cl is added to the carbon atom carrying more number of hydrogen atoms.

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Q. Predict major addition product when the following addition reaction carried out in presence of peroxide:

C_{6} H_{5} - C H = C H - C H_{3} + C C l_{4} \to

Q. The major product obtained by the addition reaction of

H B r

to 4-methylpent-1-ene in the presence of peroxide is:

Q. Assertion :Addition of HBr to propene yields 2-bromopropane but in presence of a peroxide it yields 1-bromopropane. Reason: When reaction is carried out in the presence of a peroxide it follows free radical mechanism,

2^{0}

free radical is more stable than

1^{0}

H B r

gives the same product in the presence or absence of peroxide when alkene is:

3 -

- 2 -

ene on reaction with

H B r

in presence of peroxide forms an addition product.

The number of possible stereoisomers for the products:

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Bromine Water Test

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