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Question

Predict the number of stereoisomers (optical isomers) in OHCH2(CHOH)4CHO.

A
16
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B
8
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C
4
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D
2
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Solution

The correct option is A 16
Terminal groups are different.
When the molecule has no symmetry, total no. of optical isomers = 2n
where n is number of asymmetrical carbon atom

The number of asymmetric C atoms are four.

Therefore, the number of stereoisomers (optical isomers) is
2n=24=16

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