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Question

Primary nitroalkanes are obtained in good yield by oxidizing aldoximes with the help of:

A
trifluoroperoxyacetic acid
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B
acidified potassium permanganate
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C
concentrated nitric acid
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D
potassium dichromate and dilute sulphuric acid
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Solution

The correct option is D trifluoroperoxyacetic acid
Primary nitroalkanes are obtained in good yield by oxidising aldoximes with the help of trifluoroperoxyacetic acid.
RCH=NOH+[O]trifluoroperoxyaceticacid−−−−−−−−−−−−−−−RCH=N+(O)OHRCH2NO2
Note:
Secondary nitroalkanes are obtained in good yield by oxidising ketoximes with the help of trifluoroperoxyacetic acid.

Option A is correct.

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