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Question

Pyrolusite is MnO2IMnO24IIMnO4
Steps I and II are respectively :

A
fuse with KOH / air and electrolytic oxidation.
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B
fuse with KOH/KNO3 and electrolytic oxidation.
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C
fuse with conc. HNO3/air and electrolytic reduction.
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D
dissolve in H2O and oxidation.
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Solution

The correct options are
A fuse with KOH / air and electrolytic oxidation.
B fuse with KOH/KNO3 and electrolytic oxidation.
Fuse with KOH in presence of air or oxidising agents like KNO3 , KClO3 etc.
2MnO2+4KOH+O2fuse2K2fuse2K2MnO4+2H2O
MnO24electrolytic oxidation−−−−−−−−−−−−MnO4+e

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