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Q.28 Potassium superoxide, KO2, is utilised in closed system breathing apparatus. Exhaled air contains CO2
and H2O, both of which are removed and the removal of water generates oxygen for breathing by the
reaction
4KO2(s) + 2H2O(l) -> 3O2(g) + 4KOH(s)
The potassium hydroxide removes CO2from the apparatus by the reaction :
KOH (s) + CO2(g) --> KHCO3(s)
(a) What mass of KO2 generates 20 gm of oxygen ?
(b) What mass of CO2 can be removed from the apparatus by 100 gm of KO2 ?

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Solution

Dear Student,

The computation are expressed below,


part (a)moles of KO2=20 g O232 gmol O2×4 mol KO23 mol O2=0.833 molgm of KO2=0.833 mol ×71.097 gmol = 59.224 gmpart (b)moles of CO2=moles of KO2=100 g71.097 gmol=1.407 molmass of CO2=1.407 mol×44.01 gmol=61.92 gm

Regards.

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