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Question

R−CH2−CH2OH can be converted to R−CH2CH2COOH. The correct sequence of reagents is:

A
PBr3,KCN,H3O+
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B
PBr3,KCN,H2
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C
KCN,H+
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D
HCN,PBr3,H+
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Solution

The correct option is A PBr3,KCN,H3O+
RCH2CH2OH can be converted to RCH2CH2COOH.

The correct sequence of reagents is PBr3,KCN,H3O+.

RCH2CH2OHPBr3−−RCH2CH2BrKCN−−RCH2CH2CNH3O+−−RCH2CH2COOH

Alcohol is converted to alkyl bromide. Br atom is then substituted with cyano group. Acid hydrolysis of cyano group gives final product (carboxylic acid).

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