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Question

Rate law for the reaction, A+2BC is found to be
Rate=k[A][B]
Concentration of reactant 'B' is doubled, keeping the concentration of 'A' constant, the value of rate constant will be ................. .

A
the same
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B
doubled
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C
quadrupled
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D
halved
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Solution

The correct option is A the same
From the rate law expression, it is clear that the rate w.r.t to B is of the first order.
Rate R1=k[A][B]...(i)
Rate R2=k[A][2B]...(ii)
Dividing eq.(i) by eq. (ii) =R2=2R1 ...(iii)

From (iii)
When the concentration of A is kept constant and the concentration of B gets double than the rate will be doubled.

Hence, Option "B" is the correct answer.

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