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Question

Ratio of solubilities of gases N2 & O2 in water from air at 25o and 1 atm will be if air is 20% by volume of O2 and 80% by volume of N2 is:
Given : KH(N2)=2×104atm
KH(O2)=104atm

A
8 : 1
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B
1 : 8
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C
2 : 1
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D
1 : 2
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Solution

The correct option is C 2 : 1
XN2=0.8,XO2=0.2 in air

PN2=0.8atm,PO2=0.2atm

P=KHX4 where X is solubility

0.8=2×104XN2 .......(1)

0.2=104XO2 .......(2)

Ratio of solubility of N2 & O2 is 2:1

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