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Question

Reaction of an inorganic sulphite X with dilute H2SO4 generates compound Y. Reaction of Y with NaOH gives X. Further, the reaction of X with Y and water affords compound Z. Y and Z, respectively, are

A
SO2 and NaHSO3
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B
SO2 and Na2SO3
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C
SO3 and NaHSO3
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D
S and Na2SO3
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Solution

The correct option is A SO2 and NaHSO3
X=Na2SO3

The reactions are as follows,

Na2SO3(X)+dil.H2SO4Na2SO4+H2+SO2(Y)

SO2+2NaOHNa2SO3(X)+H2O

Na2SO3+SO2+H2O2NaHSO3

Thus, Y=SO2; Z=NaHSO3

Hence, option (b) is correct.

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