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Stability of Carbocation

Reaction Of N...

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Reaction Of N,N dimethyl With HNO2 forms??

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P h N_{2}^{+} {B r}^{-}

couples with N,N-dimethyl aniline (I) but not with 2,6-dimethyl-N,N dimethyl aniline (II). Reason: Due to steric inhibition of resonance, the p-position of (II) is not sufficiently activated for the coupling reaction.

Q. An organic acid (

X

) has molecular formula

C_{8} H_{16} O_{2}

X

on heating with

N H_{3}

Y

which on treatment with alkaline

B r_{2}

Z

Z

on treatment with

H N O_{2}

followed by heating with

H_{2} S O_{4}

gives 2,4-dimethyl-2-pentene. How many different acids (

X

) can give the indicated final product?

Q. Methylamine reacts with

H N O_{2}

The set A = {5, 10, 15, 20, 25, 30} written in the set builder form is ______________________.

Q. Match the column I with column II and mark the appropriate choice.

	Column I		Column II
(A)	Aniline	(i)	Can be made by Gabriel phthalimide reaction
(B)	N-Methylaniline	(ii)	Undergoes electrophilic substitution reaction with $H N O_{2}$
(C)	N, N-Dimethylaniline	(iii)	Forms yellow oily product with $H N O_{2}$
(D)	Benzylamine	(iv)	Gives azo dye test

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