Reduction of the metal centre in aqueous permanganate ion involves :
A
3 electrons in neutral medium
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B
5 electrons in neutral medium
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C
3 electrons in alkaline medium
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D
5 electrons in acidic medium
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Solution
The correct options are A3 electrons in neutral medium C3 electrons in alkaline medium D5 electrons in acidic medium In acidic medium: MnO−4+8H++5e−→Mn2++4H2O
In neutral medium: MnO−4+2H2O+3e−→MnO2+4OH−
In basic medium: MnO−4+H2O→2MnO2+O2
MnO−4 to MnO2 means Mn from +7 to +4, i.e., 3 electrons are gained.