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Question

Reduction of the metal centre in aqueous permanganate ion involves :

A
3 electrons in neutral medium
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B
5 electrons in neutral medium
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C
3 electrons in alkaline medium
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D
5 electrons in acidic medium
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Solution

The correct options are
A 3 electrons in neutral medium
C 3 electrons in alkaline medium
D 5 electrons in acidic medium
In acidic medium:
MnO4+8H++5eMn2++4H2O

In neutral medium:
MnO4+2H2O+3eMnO2+4OH

In basic medium:
MnO4+H2O2MnO2+O2

MnO4 to MnO2 means Mn from +7 to +4, i.e., 3 electrons are gained.

Hence options A, C and D are correct.

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