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Question

Since, the enthalpy of the elements in their standard states is taken to be zero, the heat of formation (ΔHf) of compounds:

A
is always negative
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B
is always positive
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C
is zero
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D
may be positive or negative
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Solution

The correct option is C may be positive or negative
Enthalpy of elements in their standard states is taken to be zero, but the heat of formation of compounds depends on the enthalpy of compounds formed at standard states which can be both negative as well as positive.
Their is no restriction over enthalpy of compounds formed at standard state.
Hence, the value of heat of formation can also of any positive or negative value.
Hence, answer is option D.

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