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"Sodium metal when dissolved in ammonia conducts electricity because of solvated electrons."
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Solution

Sodium metal when dissolved in ammonia conducts electricity because of solvated electrons.
Sodium metals when dissolved in ammonia gives a conducting blue coloured solution due to the presence of solvated electrons (e,NH3), which are not attached to single atoms. A solvated electron is loosely associated with a cavity in the ammonia solvent that is stabilized by hydrogen bonds. In dilute solutions, the cation appears to be Na+, probably solvated as Na(NH3)m+, and anion NH3 or (NH3)n which also contributes the colour.
The presence of solvated electrons (e,NH3) in solutions of alkali metals in liquid ammonia is indicated by the intense color of the solution and its electrical conductivity.

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