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Question

Solid ammonium carbamate, NH2CO2NH4(s), dissociates into ammonia and carbon dioxide when it evaporates as shown below:
NH4CO2NH2(s)2NH3(g)+CO2(g)
At 25C, the total pressure of the gases in equilibrium with the solid is 0.116atm. If 0.1 atm of CO2 is introduced after equilibrium is reached then:

A
final pressure of CO2 be less than 0.1atm
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B
final pressure of CO2 will be more than 0.1atm
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C
pressure of NH3 will decrease due to addition of CO2
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D
pressure of NH3 will increase due to addition of CO2
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Solution

The correct options are
B final pressure of CO2 will be more than 0.1atm
C pressure of NH3 will decrease due to addition of CO2
The pressure of NH3 will decrease due to addition of CO2(backward, shifting Le-chatelier's principle. The pressure of CO2 will be more than 0.1 atm.

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