Some hydrogen-like atom in ground state absorb n photons having the same energy and on de-excitation, it emits exactly n photons. Then the energy of absorbed photon may be:
A
91.8eV
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B
40.8eV
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C
48.4eV
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D
54.4eV
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Solution
The correct options are A91.8eV B40.8eV Solution:- (A) 91.8eV and (B) 40.8eV
As we know that,
E=13.6×Z2[1n12−1n22]
Number of dark lines (in absorption) i.e excitation = number of bright lines (in emission),i.e de-excitation
It is possible only when the e− is excited from n=1 to n=2.
Therefore,
E=13.6×Z2[112−122]
⇒E=13.6×Z2[1−14]
⇒E=10.2Z2
Now,
For Z=1
E=10.2×(1)2=10.2
For Z=2
E=10.2×(2)2=40.8
For Z=3
E=10.2×(3)2=91.8
Hence the correct answer is (A)91.8eV and (B)40.8eV.