Specific conductance of 0.1 M HA is 3.75×10−4ohm−1cm−1. If λ∞(HA)=250 ohm−1cm2mol−1, the dissociation constant Ka of HA is :
1.0×10−5
2.25×10−4
2.25×10−5
2.25×10−13
λm=1000k0.1=1000×3.75×10−40.1=3.75;α=λmλ∞m=3.75250=1.5×10−2;Ka=Cα2=0.1×(1.5×10−2)2=2.25×10−5
Specific conductance of 0.1 MCH3COOH at 25∘ is 3.9×10−4ohm−1cm−1. If λ∞(H3O+) and λ∞(VH3COO−) at 25∘C are 349.0 and 41.0 ohm−1cm2mol−1 respectively, degree of ionization of CH3COOH at the given concentration is :