Starting from aniline how will you prepare benzene diazonium chloride and chlorobenzene from the later? Explain giving chemical reactions involved.
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Solution
Diazotization of Aniline with NaNO2/HCl gives Benzene diazonium chloride. Sandmeyer reaction converts benzene diazonium chloride to chlorobenzene. This reaction is carried out in presence of Cu+HCl.