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Nature of Oxides

Strongest C-O...

Question

Strongest C-O bond will be in:

A

[M n (C O)_{6}]^{+}

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B

[C r (C O)_{6}]

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C

[V (C O)_{6}]^{-}

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D

Same in all

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Solution

The correct option is A $[M n (C O)_{6}]^{+}$

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Similar questions

Q. Among the metal carbonyls

[M n (C O)_{6}]^{+}, [T i (C O)_{6}], [C r (C O)_{6}]

[V (C O)_{6}]^{-}

C - O

bond order would be lowest in :

Q. In which complex is the

C - O

bond length maximum?

Q. Consider the following complexes

[V (C O)_{6}]^{-}, [C r (C O)_{6}]

[M n (C O)_{6}]^{+}

. Then incorrect statement(s) about metal carbonyls is /are

I R

stretchin frequencies of free

C O

C O

[V (C O)_{6}]^{-}, [C r (C O)_{6}]^{-}

[M n (C O)_{6}]^{-}

2143 c m^{- 1}, 1860 c m^{- 1}, 2000 c m^{- 1}

2090 c m^{- 1}

, respectively. Then correct statement about metal carbonyls is?

Which of the following has longest C-O bond length? (Free C-O bond length in CO is 1.128 A.)

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