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Question

Structure of (B) is :

A
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B
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C
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D
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Solution

The correct option is A
In the given substrate both aldehyde groups does not have a α-hydrogen so it undergo cannizzaro reaction in presence of strong base. Also both aldehyde groups are in single substrate. Hence, it is a intramolecular cannizzaro reaction.
In this reaction one aldehyde group get reduced to alcohol and one oxidised to carboxylic acid.
Formed product on acidification form cyclic ester (lactones).

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