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Question

Sumit evacuated a cylinder and filled in 4g of gas A at temperature 25oC. The pressure was found to be 1atm. His friend Vineet, filled another 8g of gas B in the cylinder at the same temperature. The final pressure was found to be 1.5atm. The ratio of molecular masses of A and B (assuming ideal gas behaviour) is ____.

A
1:1
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B
1:2
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C
1:8
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D
1:4
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Solution

The correct option is D 1:4
Option D.
Using PV=nRT for gas A.
1×V=nART
V=(4MA)RTi.
After addition of gas B,
1.5V=(4MA+8MB)RTii
(2)(1)1.5=(4MA+8MB)MA4=1+2MAMB
0.5=2MAMB
MAMB=0.52=12×2=14

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