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Question

Suppose two elements X and Y combine to form two compounds XY2 and X3Y2. 0.1 mol of former weighs 10 g while 0.05 mol of the latter weighs 9 g. The atomic masses of X and Y are, respectively:

A
60 and 40
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B
30 and 40
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C
40 and 30
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D
40 and 60
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Solution

The correct option is D 40 and 30
The molecular weight of XY2=100.1=100 g/mol.
The molecular weight of X3Y2=90.05=180 g/mol.
Let a and b represent the atomic masses of X and Y respectively.
The molecular weight of XY2=a+2b=100 g/mol.
The molecular weight of X3Y2=3a+2b=180 g/mol.
On solving these two equations, we get a=40 and b=30.

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