The absolute enthalpy of neutralisation of the reaction will be:
MgO(s)+2HCl(aq)→MgCl2(aq)+H2O(l)
A
+57.33kJmol−1
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B
−57.33kJmol−1
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C
greater than −57.33kJmol−1
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D
less than −57.33kJmol−1
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Solution
The correct option is C greater than −57.33kJmol−1 The absolute value of enthalpy of neutralization of this reaction is greater than −57.33kJmol−1.
This is due to the very high enthalpy of hydration of Mg2+ ion. The change in enthalpy of this reaction is nearly -146 kJ.
Thus enthalpy of neutralization per mole of H+ ion is nearly -73 kJ, which is greater than the enthalpy of neutralization strong acid against strong base i.e. -57.33 kJ.