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Question

The absolute enthalpy of neutralisation of the reaction will be:
MgO(s)+2HCl(aq)MgCl2(aq)+H2O(l)

A
+57.33 kJ mol1
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B
57.33 kJ mol1
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C
greater than 57.33 kJ mol1
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D
less than 57.33 kJ mol1
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Solution

The correct option is C greater than 57.33 kJ mol1
The absolute value of enthalpy of neutralization of this reaction is greater than 57.33 kJmol1.
This is due to the very high enthalpy of hydration of Mg2+ ion. The change in enthalpy of this reaction is nearly -146 kJ.

Thus enthalpy of neutralization per mole of H+ ion is nearly -73 kJ, which is greater than the enthalpy of neutralization strong acid against strong base i.e. -57.33 kJ.

Hence, the correct answer is an option (C).

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