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Question

The action of bleaching powder on ethyl alcohol gives :

A
CCl4
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B
CHCl3
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C
COCl
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D
Ether
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Solution

The correct option is B CHCl3
Chloroform CHCl3 and calcium formate Ca(COOH)2 are formed when bleaching powder reacts with ethyl alcohol.
Ca(OCl)Cl+H2OCl2+Ca(OH)2
CH3CH2OH+Cl2CH3CHO+2HCl
CH3CHO+3Cl2CCl3CHO+3HCl
2CCl3CHO+Ca(OH)22CHCl3+Ca(COOH)2

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