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Question

The addition of 0.1 mole of KBr to an aqueous solution containing 0.05 moles of AgNO3 results in the formation of an insoluble white precipitate of AgBr. Find the amount of AgBr that gets formed.
(Ag=108 u, Br=80 u)

A
9.4 g
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B
4.7 g
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C
7.8 g
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D
8.2 g
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Solution

The correct option is A 9.4 g
The corresponding reaction is:
KBr(aq)+AgNO3(aq)KNO3(aq)+AgBr(s)
Moles of KBr=0.1 mol
Moles of AgNO3=0.05 mol
From the balanced stoichiometric equation,
1 mole of KBr reacts with 1 mole of AgNO3
0.1 moles of KBr will react with 0.1 moles of AgNO3
So, AgNO3 is the limiting reagent.
As per the reaction, 1 mole of AgNO3 produces 1 mole of AgBr.
0.05 moles of AgNO3 will produce 0.05 moles of AgBr.
Amount of precipitate formed
=moles of AgBr formed × Molar mass of AgBr
=(0.05×188) g
=9.4 g

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