The amount of ice in grams that will separate out on cooling a solution containing 50 g of a non volatile solute - ethylene glycol in 200 g of water to −9∘C is: (Kf for water = 1.86 Kkgmol−1 )
A
48.20 g
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B
33.33 g
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C
37.19 g
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D
4.27 g
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Solution
The correct option is B 33.33 g △Tf=Kf×w1×1000M1×w2⇒9=1000×1.86×5062×w2⇒w2=166.67 g ∴ weight of ice separated =200−166.67=33.33g