The correct option is D Clostridium
Plants cannot absorb atmospheric nitrogen directly. They absorb nitrogen in the form of ammonium, nitrate and nitrite ions. Azotobacter species are free-living, nitrogen-fixing bacteria; in contrast to Rhizobium species, they normally fix molecular nitrogen from the atmosphere without symbiotic relations with plants, although some Azotobacter species are associated with plants. Clostridium is anaerobic nitrogen fixer.