Synthesis of Aldehydes or Ketones from Hydrocarbons
The best oxid...
Question
The best oxidising agent for oxidation of CH3−CH=CH−CHO to CH3−CH=CH−COOH is :
A
Baeyer's reagent
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B
Tollens' reagent
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C
Schiff's reagent
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D
Acidified dichromate
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Solution
The correct option is B Tollens' reagent Since dichromates are powerful oxidising agents, they can oxidize double bond also, to protect double bond, we use mild oxidising agent as Tollen's [Ag(NH3)2]+OH− which oxidises aldehyde to acids and Ag(0) (mirror) is precipitated.