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Question

The blue colour in an oxidising flame of a microcosmic bead containing Cu2+ is due to:

A
NaCuPO4
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B
Cu(PO)4
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C
Cu3(PO4)2
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D
None of the above
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Solution

The correct option is A NaCuPO4
Microcosmic salt bead test is a test similar to borax bead test and is used for the identification of coloured cations if microcosmic salt, Na(NH4)HPO4.4H2O is used.
The involved reactions are given below:
Na(NH4)HPO4.4H2OΔNaPO3+H2O (g)+NH3 (g)
Transparent bead
NaPO3+CuONaCuPO4
Blue bead

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