The boiling point of Sb is greater than Bi.Sb is greater than Bi.
1. The b.p. of Sb is greater than Bi.
2. Group 15 elements consists of 5 valence electrons.
3. Now the melting point of group 15 elements increases as we move down the group from N to As these elements have tendency to involve all the 5 electron both s and p orbital in bonding but as we move down the group from Sb to Bi, the s orbital electron do not involve in bonding due to inert pair effect which doesn't allow extra two electron to involve in bonding .
4. Thus Melting and boiling point decreases as move from Sb to Bi.