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Question

The boiling point of Sb is greater than Bi.Sb is greater than Bi.

A
True
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B
False
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Solution

The correct option is A True

1. The b.p. of Sb is greater than Bi.

2. Group 15 elements consists of 5 valence electrons.

3. Now the melting point of group 15 elements increases as we move down the group from N to As these elements have tendency to involve all the 5 electron both s and p orbital in bonding but as we move down the group from Sb to Bi, the s orbital electron do not involve in bonding due to inert pair effect which doesn't allow extra two electron to involve in bonding .

4. Thus Melting and boiling point decreases as move from Sb to Bi.


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