The carbon-based reduction method is NOT used for the extraction of
Aluminum from Al2O3
Magnesium from MgCO3.CaCO3
The oxides of the less electropositive metals are reduced by strongly heating them with coke. Both Iron and Tin oxides can be profitably smelted using Carbon. Aluminium is extracted by the molten electrolysis (non-aqueous) of alumina with fluorspar and cryolite.
Likewise, molten salt electrolysis of MgCl2 yields metallic Magnesium.