The CFSE for octahedral [CoCl6]4− is 18,000cm–1.
The CFSE for tetrahedral [CoCl4]2− will be
A
18,000cm–1
No worries! We‘ve got your back. Try BYJU‘S free classes today!
B
16,000cm–1
No worries! We‘ve got your back. Try BYJU‘S free classes today!
C
8,000cm–1
Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses
D
20,000cm–1
No worries! We‘ve got your back. Try BYJU‘S free classes today!
Open in App
Solution
The correct option is C8,000cm–1 The crystal field splitting in the tetrahedral field is intrinsically smaller than in the octahedral field. For most purposes the relationship may be represented as Δt=49Δo Δt=49(18000cm−1)=8000cm−1