The correct option is D CV4
Consider the case of open key
1Ceq.=1C+1C+C+C
=1C+13C
=43C
Ceq.=3C4
Thus, initial charge flown (qi)=34CV
Now, consider the case of closed key.
Net capacitance of this case is C.
Charge flown (qf)=CV
∴Δq=qf−qi
=CV−34CV
=14CV
Hence, charge passed through cell is 14CV.