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Question

The complex ion [Co(H2O)5(ONO)]2+ and [Co(H2O)5NO2]2+ are called :

A
linkage isomer
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B
ionization isomer
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C
co-ordination isomer
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D
geometrical isomer
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Solution

The correct option is A linkage isomer
In Linkage isomerism, the same ligand is bonded to central metal atom or ion through different atoms. The given question is the case of linkage isomerism as is bonded to a different atom of the same ligand i.e. O and N.

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