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Question

The complexes [Pt(NH3)4][PtCl6] and [Pt(NH3)4Cl2][PtCl4] are:

A
linkage isomers
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B
optical isomers
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C
co-ordination isomers
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D
ionisation isomers
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Solution

The correct option is C co-ordination isomers
Coordination isomerism: Compounds containing complex anionic and cationic parts can be thought of as occurring by the interchange of some ligands from the cationic part to the anionic part.

Therefore, the given compounds possess coordination isomerism.

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