The correct option is C Al2O3
Barrring aluminium, all the other metals here show at least 3 oxidation states, which would make it possible for them to act as both oxidising and reducing agents.
S:0,+4,+6Mn:0,+2,+4,+6,+7Al:0,+3Cr:0,+3,+6
Hence, Al2O3 cannot act as oxidizing as well as reducing agent.