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Question

The compounds below have the most basic nitrogen atom circled. Pick the compounds that are correctly labelled.

A
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B
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C
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D
All of these
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Solution

The correct option is D All of these
(a) Circled N is sp3 hybridised and lone pair is not involved in resonance.
(b) Circled N sp3 hybridised and its lone pair is relatively easily available than others where lone pairs are involved in resonance with benzene ring.
(b) N in Pyridine is more basic than pyrrole. It is due to involvement of lone pair of nitrogen in pyrrole in aromaticity.

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