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Question

The compressibility factor Z for the gas at 327oC and 60.375 atm pressure is :

A
1.226
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B
1
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C
0.226
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D
1.456
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Solution

The correct option is A 1.226
Given,

Cp=0.125 cal/g,Cv=0.075 cal/g
Also as we know,
CpCv=RM
M=20.1250.075=40 so molar mass of gas is 40.
Also, CpCv=0.1250.075=53=1.66, so gas is monoatomic, also molar mass of gas is 40 so gas is Ar.

And n=wM=20040=5
Also, compressibility factor Z

Z=PVnRT=60.375×55×0.0821×600=1.226

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