The conductivity of 0.20M solution of KCl at 298K is 0.0248 S cm−1. Calculate its molar conductivity ?
Conductivity (k)=0.0248 S cm−1=0.0248 ohm−1cm−1
Molar concentration (C) 0.20 mol L−1
=(0.2 mol)(1000 cm3)=2.0×10−4molcm−3
Molar conductivity (λm)=kC=(0.0248 ohm−1)cm−1(2.0×10−4mol cm−3)
=124 ohm−1mol−1cm2
or 124 S mol−1cm2
Molar conductivity 124 S mol−1cm2