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Question

The correct order of basicity of the following amines

A
I>II>III>IV
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B
I>III>II>IV
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C
III>II>I>IV
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D
IV>III>II>I
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Solution

The correct option is B I>III>II>IV
I- Lone pair of 'N' doesn't involved in resonance
II- Lone pair of 'N' is involved in resonance
III- Lone pair of 'N' is involved in resonance and also basicity is increased due to +I effect of CH3 group
IV- Lone pair of 'N' is involved in resonance and also basicity decreases due to -I effect of NO2 group

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