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Question

The correct order of increasing bond angles in the following species is:

A
Cl2O<ClO2<ClO2
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B
ClO2<Cl2O<ClO2
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C
Cl2O<ClO2<ClO2
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D
ClO2<Cl2O<ClO2
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Solution

The correct option is C Cl2O<ClO2<ClO2
The correct order of increasing bond angles in the following species is
Cl2O<ClO2<ClO2
This is because, In ClO2 there are two lone pairs of electrons which repel each other due to which two oxygen atom come closer leading to decrease in bond angle. Therefore the bond angle in ClO2 is less than 118° which is bond angle in ClO2 which has less number of electrons on chlorine.

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