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Question

The correct order of increasing bond angles in the following species is:

A
NO2<NO+2<NO2
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B
NO2<NO2<NO+2
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C
NO+2<NO2<NO2
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D
NO+2<NO2<NO2
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Solution

The correct option is B NO2<NO2<NO+2

NO2 and NO2 are sp2 hybridized. Since NO2 has lone pair-bond pair repulsion so the angle is smaller than NO2.
NO+2 is sp hybridized.

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