The correct order of strength of acidity of the following compounds is:
A
(ii) > (i) > (iii) > (iv)
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B
(i) > (ii) > (iii) > (iv)
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C
(iv) > (iii) > (ii) > (i)
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D
(iv) > (iii) > (i) > (ii)
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Solution
The correct option is C (iv) > (iii) > (i) > (ii) Presence of electron withdrawing groups such as nitro group enhance the acidic strength of phenol and the presence of electron releasing groups such as alkyl group decreases the acidic strength of phenol.
As NO2 shows −R effect so increases acidity while CH3 shows +I effect, hence decreases acidity.