The correct relationship between the boiling points of very dilute solutions of $A l C l_{3} (t_{1})$ and $C a C l_{2} (t_{2})$ , having the same molar concentration, is :

t_{1} = t_{2}

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t_{1} > t_{2}

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t_{2} > t_{1}

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t_{2} \geq t_{1}

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Solution

The correct option is A $t_{1} > t_{2}$
The correct relationship between the boiling points of very dilute solutions of $A l C l_{3} (t_{1})$ and $C a C l_{2} (t_{2})$ , having the same molar concentration, is $t_{1} > t_{2}$ .
$A l C l_{3}$ furnishes more ions(3 ions) than $C a C l_{2}$ (2 ions) and thus, shows higher boiling point.

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