The correct relationship between wave numbers of spectral lines, in Balmer series of hydrogen atom having the least and highest wave - lengths, is given by
9 : 5
In the Balmer series of hydrogen atom the highest wave length is that of first line and the least wave length is that of limiting line, thus
¯℧∞¯℧1=1(2)2−1(∞)21(2)2−1(3)2=14−0(9−436)=14×365=95
or 9 : 5