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Standard XIII

Chemistry

Shapes of Orbitals and Nodes

The d-orbital...

Question

The d-orbital which has the maximum electronic probability density along two axes is:

d_{x^{2} - y^{2}}

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d_{z^{2}}

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d_{x y}

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d_{x z}

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Solution

The correct option is A $d_{x^{2} - y^{2}}$
$d_{x^{2} - y^{2}}$ has probability density along x and y axes.
$d_{z^{2}}$ has probability density along z-axis.
$d_{x y}$ and $d_{x z}$ has probability density in between the axes.

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Q. The

^{'} d^{'}

-orbital having maximum electron density along two axes is:

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Q. Which of the following set of orbitals may have electron density along the axes?

Q. Which of the following pairs of d-orbitals have electron density along the axes ?

Question 03

The probability density plots of 1s and 2s orbital are given in figure.

The density of dots in region represents the probability density of finding electrons in the region. On the basis of above diagram which of the following statements is incorrect ?

(a) 1s and 2s orbitals are spherical in shape

(b) The probability of finding electron is maximum near the nucleus

(d) The probability density of electrons for 2s orbital decreases uniformly as distance from the nucleus increases

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Shapes of Orbitals and Nodes

Standard XIII Chemistry

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The d-orbital which has the maximum electronic probability density along two axes is:

The correct option is A dx2−y2dx2−y2 has probability density along x and y axes. dz2 has probability density along z-axis. dxy and dxz has probability density in between the axes.

The correct option is A $d_{x^{2} - y^{2}}$
$d_{x^{2} - y^{2}}$ has probability density along x and y axes.
$d_{z^{2}}$ has probability density along z-axis.
$d_{x y}$ and $d_{x z}$ has probability density in between the axes.