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Question

The decreasing order of the bond angles in NO2,NO+2, and NO2 is

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Solution

NO+2 has a linear structure and has a bond angle of 180 . Both NO2 and NO2 are bent but NO2 has an odd electron on N while NO2 has the presence of a complete lone pair that repels the bond pairs further and hence the bond angle is lesser in it. Therefore, the order is NO+2>NO2>NO2

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