The ΔH value at 360 K for the reaction: Fe2O3(s)+3H2(g)→2Fe(s)+3H2O(l), given that ΔH300=−33.29kJmol−1 and Cp for Fe2O3(s), Fe(s), H2O(l) and H2(g) are 103.8,25.1,75.3 and 28.8 JK−1mol−1, is:
△Cp=Cp(Products)−Cp(Reactants)
ΔCp=(2×25.1)+(3×75.3)−(103.8+3(28.8))=85.9JK−1mol−1
ΔH2−ΔH1T2−T1=ΔCp
ΔH360−(−33290)360−300=85.9
ΔH360=−28136Jmol−1=−28.136kJmol−1