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Question

The ΔH value at 360 K for the reaction: Fe2O3(s)+3H2(g)2Fe(s)+3H2O(l), given that ΔH300=33.29kJmol1 and Cp for Fe2O3(s), Fe(s), H2O(l) and H2(g) are 103.8,25.1,75.3 and 28.8 JK1mol1, is:

A
28.1 kJmol1
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B
28.1 kJmol1
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C
85.9 kJmol1
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D
85.9 kJmol1
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Solution

The correct option is A 28.1 kJmol1

Cp=Cp(Products)Cp(Reactants)

ΔCp=(2×25.1)+(3×75.3)(103.8+3(28.8))=85.9JK1mol1


ΔH2ΔH1T2T1=ΔCp


ΔH360(33290)360300=85.9


ΔH360=28136Jmol1=28.136kJmol1


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