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Question

The density of 3M solution of sodium thiosulphate (Na2S2O3) is 1.58 g/ml., Calculate mole fraction of Na2S2O3.

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Solution

Here,Molarityis3MDensity(d)is1.589gmlHeresoluteisNa2S2O3MolecularMassofsolute(Ma)=1589SolventisH2OM.Mofsolvent(Mb)=189weknowMolarity=XBd×1000XAMA+XBMB3=(1xA)×1.58×1000xA(158)+(1xA)(18)474xA+5454xA=15801580xA2000xA=1526xA=15262000=0.763Molefractionis0.763

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