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Question

The E for OCl|Cl and Cl|12Cl2 are 0.94V and 1.36V.E for OCl|12Cl2 is:

A
0.42V
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B
2.20V
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C
0.52V
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D
1.04V
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Solution

The correct option is C 0.52V
OCl+2eCl E0OCl/Cl=0.94V........(1)
Cl12Cl2+e E0Cl/12Cl2=1.36V......(2)
OCl+e12Cl2 E0OCl/12Cl2=?.........(3)
G03=G01+G021×F×E03=2×F×0.941×F×(1.36)E3=2×0.941.36=0.52V

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